Metastable ion study of organosilicon compounds. Part IX. CH 3 COOSi (CH 3) 3 and CF 3 COOSi (CH 3) 3

S Mori, F Okada, O Sekiguchi, M Fujishige…

文献索引：Mori, Shigeru; Okada, Fumio; Sekiguchi, Osamu; Fujishige, Masao; Koitabashi, Risei; Tajima, Susumu Journal of Organometallic Chemistry, 1997 , vol. 527, # 1-2 p. 277 - 282

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被引用次数: 11

摘要

The unimolecular metastable dissociation of trimethylsilyl acetate, CH3COOSi (CH3) 3 (1), and its fluorine analogue, trimethylsilyl trifluoroacetate, CF3COOSi (CH3) 3 (2), upon electron impact have been investigated by means of a B/E linked scan, high resolution data, and D-labeling. The results are compared with those of the carbon analogue, tert-butyl acetate, CH3COOC (CH3) 3 (3). No molecular ion of any of these compounds can be ...