A rationally designed universal catalyst for Suzuki–Miyaura coupling processes

…, TE Barder, JR Martinelli, SL Buchwald

文献索引：Walker, Shawn D.; Barder, Timothy E.; Martinelli, Joseph R.; Buchwald, Stephen L. Angewandte Chemie - International Edition, 2004 , vol. 43, # 14 p. 1871 - 1876

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被引用次数: 818

摘要

Despite advances in the Suzuki–Miyaura cross-coupling process,[1] the need for an operationally simple and general system remains. The minimum criteria for an optimum system that must be met include: 1) a broad substrate scope, 2) the ability to make truly hindered biaryls, 3) the ability to operate at low levels of catalyst for a range of substrates not just with the most simple examples (eg, other than phenyl boronic acid),[2] and 4) the ...