Accounts of chemical research

Unequivocal SRN1 route of vinyl halides with a multitude of competing pathways: Reactivity and structure of the vinyl radical intermediate

C Galli, Z Rappoport

文献索引：Galli, Carlo; Gentili, Patrizia Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1993 , # 6 p. 1135 - 1140

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被引用次数: 39

摘要

Unambiguous examples of the vinylic SRN1 reaction initiated by a single-electron transfer from an electron-donor anion (Y-) to a suitable VyX substrate, and proceeding through a vinyl radical (Vy) intermediate, are described. Competition by alternative substitution routes