Kinetics of the reduction of isoquinolinium cations by 1, 4-dihydronicotinamides

JW Bunting, VSF Chew, G Chu

文献索引：Bunting, John W.; Chew, Vivian S. F.; Chu, Gary Journal of Organic Chemistry, 1982 , vol. 47, # 12 p. 2303 - 2307

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被引用次数: 25

摘要

Results Pseudo-first-order rate constanta (how) for the reaction of l-benzyl-1, 4- dihydronicotinamide (5) with the 2-methylisoquinolinium cation (4 (X= H)) and its 4-bromo derivative (4 (X= Br)) as a function of isoquinolinium cation concentration display kinetic saturation effects. Double-reciprocal plots of these data are linear (Figure 1) and may be characterized by slope and ordinate intercept