Dual effect of halides in the Stille reaction: in situ halide metathesis and catalyst stabilization

S Verbeeck, C Meyers, P Franck…

文献索引：Verbeeck, Stefan; Meyers, Caroline; Franck, Philippe; Jutand, Anny; Maes, Bert U. W. Chemistry - A European Journal, 2010 , vol. 16, # 43 p. 12831 - 12837

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被引用次数: 25

摘要

Abstract Halide anions can increase or decrease the transmetallation rate of the Stille reaction through in situ halide metathesis. Although the influence of the halogen present in oxidative addition complexes on the transmetallation rate with organostannanes was already known, the application of in situ halide metathesis to accelerate cross-coupling reactions with organometallic reagents is not described in the literature yet. In addition a ...