" Spontaneous" formation of radicals from nitroso compounds. Inadvertent photolysis vs. molecule assisted homolysis

C Chatgilialoglu, KU Ingold

文献索引：Chatgilialoglu, C.; Ingold, K. U. Journal of the American Chemical Society, 1981 , vol. 103, # 16 p. 4833 - 4837

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被引用次数: 45

摘要

Abstract: The formation of radicals by a “spontaneous” reaction between nitroso compounds and certain organic materials has often been reported in the literature and has generally been ascribed to a process of molecule assisted homolysis (MAH). Some selected ': spontaneous” radical-forming processes involving trifluoronitrosomethane, nitrosobenzene, and 2, 4, 6-trichloronitrosobenzene have been reexamined. In many cases it has been ...