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New aspects of the telluroxide elimination: a facile elimination of sec-alkyl phenyl telluroxide leading to olefins, allylic alcohols, and allylic ethers

S Uemura, S Fukuzawa

文献索引:Uemura, Sakae; Fukuzawa, Shin-ichi Journal of the American Chemical Society, 1983 , vol. 105, # 9 p. 2748 - 2752

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被引用次数: 47

摘要

Abstract: The utility of the telluroxide for olefin synthesis, a reaction which previously appeared to be of little value, is described. Treatment of sec-alkylphenyltellurium dibromides, except for the cyclohexyl system, with aqueous NaOH at room temperature affords olefins, allylic alcohols, and/or allylic ethers in high yields presumably via the formation of sec-alkyl phenyl telluroxides and their facile telluroxide elimination. As to the ...

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