Competition between carbon monoxide and alkenes in chloro complexes of platinum (II)

DB Dell'Amico, R Bini, F Calderazzo…

文献索引：Dell'Amico, Daniela Belli; Bini, Riccardo; Calderazzo, Fausto; Carbonaro, Laura; Labella, Luca; Vitullo, Anna Organometallics, 2005 , vol. 24, # 18 p. 4427 - 4431

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被引用次数: 10

摘要

Alkenes (cyclohexene or 1-octene) and dienes (cyclo-octadiene, COD; or norbornadiene, NBD) react with cis-PtCl2 (CO) 2, leading, respectively, to partial and complete displacement of coordinated carbon monoxide. The reactions have been monitored by gas-volumetric methods and by IR and NMR spectra. Thermodynamic data were obtained by IR and UV spectroscopies.