Oxygen transfer from oxaziridines: a chemical model for flavin-dependent monooxygenases

…, DM Spero, WH Rastetter

文献索引：Wagner, William R.; Spero, Denice M.; Rastetter, William H. Journal of the American Chemical Society, 1984 , vol. 106, # 5 p. 1476 - 1480

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被引用次数: 10

摘要

Abstract: The ability of several aryloxaziridines to transfer an oxygen atom to phenolates was examined. 2-b-Nitro-phenyl)-3-tert-butyloxaziridine (1) was found to oxidize potassium 2, 6- dialkylphenolates to the corresponding p-benzoquinones. Product studies and an observed ESR signal suggest an electron-transfer mechanism for these oxidations. 180-Labeled oxaziridine 30 was prepared. Oxidations of phenolates with 30 rigorously establish the ...