Intermolecular Hydrogen–Fluorine Interaction in Dimolybdenum Triply Bonded Complexes Modified by Fluorinated Formamidine Ligands for the Construction of 2D?? …
…, S Inoue, M Driess, S Enthaler
文献索引：Krackl, Sebastian; Inoue, Shigeyoshi; Driess, Matthias; Enthaler, Stephan European Journal of Inorganic Chemistry, 2011 , # 13 p. 2103 - 2111
Abstract The formamidines ArNHC (H)= N–Ar [Ar= Ph (2a), 4-F-Ph (2b), 3, 5-F 2 Ph (2c) and 2, 6-F 2 Ph (2d) and R= 2, 3, 5-F 3 Ph (2e), 3, 4, 5-F 3 Ph (2f), F 5 Ph (2g) and 4-CF 3 Ph (2h)] were synthesized and the influence of the introduction of a fluorine or a trifluoromethyl group into the aryl unit on the solid-state structures was investigated. On comparing the experimental data, only marginal differences in the geometrical and electronic features of ...
