Unsymmetrical alkenes by carbene coupling from diazirine decomposition in the presence of diazo compounds

…, KE Bassett, JW Terpstra, SN Mahapatro

文献索引：Doyle, Michael P.; Devia, Alvaro H.; Bassett, Kathlene E.; Terpstra, Jan W.; Mahapatro, Surendra N. Journal of Organic Chemistry, 1987 , vol. 52, # 8 p. 1619 - 1621

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被引用次数: 16

摘要

resulted in nearly quantitative azine formation, decomposition of an equimolar mixture of these two diazirines produced the carbene dimer from this reactant combination without azine. The mixed carbene dimer was proposed to have resulted from nucleophilic attack of 1- phenyldiazoethane, presumed to have been formed from 3-methyl-3-phenyl-diazirine, on chlorophenylcarbene (eq