Chemical Communications

Mechanistic insights into a copper–disulfide interaction in oxidation of imines by disulfides

J Srogl, J Hývl, Á Révész, D Schröder

文献索引：Srogl, Jiri; Hyvl, Jakub; Revesz, Agnes; Schroeder, Detlef Chemical Communications, 2009 , # 23 p. 3463 - 3465

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被引用次数: 21

摘要

Copper-catalyzed oxidations have been at the center of chemists' interest for several decades. Coupled with molecular oxygen in an aerobic media 1 or with peroxides in anaerobic systems, 2 copper-catalyzed oxidations have become cornerstones of analytical, biological, and organic chemistry. While the oxidations have been generally accepted as a valuable tool, the nature of the reaction intermediates and the reaction mechanisms have, despite great ...