REACTIONS OF AMINES. VI. SYNTHESIS OF α-AMINO KETONES AND ACIDS FROM IMINO DERIVATIVES1, 2

HE Baumgarten, JE Dirks, JM Petersen…

文献索引：Baumgarten,H.E. et al. Journal of the American Chemical Society, 1960 , vol. 82, p. 4422 - 4423

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被引用次数: 10

摘要

These two experiments taken together and with that of Alt and Knowles4 would appear to establish fairly definitely that both the N-chloroketimine and the azirine (or some closely related aziridine derivative) are intermediates in the rearrangement of N, N-dichloro-sec- alkylamines. Ethylphenylketimine (IVb) was prepared from the reaction of ethylmagnesium bromide with benzonitrile in approximately 65y0 yield6 and subjected to the halogenation ...