Tetrahedron letters

Carbonylation of dialkylcyanocuprates with carbon monoxide: Synthesis of α-hydroxyketones

GW Kabalka, NS Li, S Yu

文献索引：Kabalka, George W.; Li, Nan-Sheng; Yu, Su Tetrahedron Letters, 1997 , vol. 38, # 13 p. 2203 - 2206

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被引用次数: 8

摘要

George W. Kabalka,' Nan-Sheng Li, and Su Yu ... Departments of Chemistry and Radiology The University of Tennessee Knoxville, TN 37996-1600 ... Abstract: Dialkylcyanocuprates, prepared from copper(l) cyanide and the corresponding alkyllithium or Gringard reagents, readily react with carbon monoxide in the presence of tri-n-butylphosphine ... The transformation of organometallic reagents into useful synthetic intermediates has played an important role in synthetic ...