The Journal of Organic Chemistry

Calixarenes. 7. p-Phenylcalix [4] arene

CD Gutsche, HN Kwang

文献索引：Gutsche, C. David; No, Kwang Hyun Journal of Organic Chemistry, 1982 , vol. 47, # 14 p. 2708 - 2712

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被引用次数: 39

摘要

p-Phenylcalix [4] arene (1 l), in the cone conformation, is a basket-shaped compound containing a large cavity and, therefore, is of interest for studies of host-guest complexation. Ita unequivocal synthesis has been achieved by the stepwise method of Hayes and Hunter, by starting with 2-bromo-4-phenylphenol and adding methylene and p-phenylphenol groups sequentially until a linear tetramer (9) is attained. Removal of the bromine followed by acid ...