Synlett

A general and efficient protocol for the synthesis of biaryl ethers from aryl silyl ethers using Cs2CO3

SL Cui, ZY Jiang, YG Wang

文献索引：Cui, Sun-Liang; Jiang, Zhi-Yong; Wang, Yan-Guang Synlett, 2004 , # 10 p. 1829 - 1831

被引用次数: 4

摘要

Abstract A general and efficient one-step procedure has been developed for the synthesis of biaryl ethers via direct coupling of electron-deficient arylhalides or aryl triflates to aryl t- butyldimethyl-silyl (TBS) ethers using Cs 2 CO 3. The protocol was also applied to electron- rich arylhalides by addition of a catalytic amount of copper (I) iodide. The reaction is rapid and provides good to excellent yields.

~88%

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~90%

~89%

~91%

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~70%

~69%

~90%

~86%

~74%

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