Mechanistic investigations of bipyrimidine-promoted palladium-catalyzed allylic acetoxylation of olefins

BL Lin, JA Labinger, JE Bercaw

文献索引：Lauer, Matthew G.; Henderson, William H.; Awad, Amneh; Stambuli, James P. Organic Letters, 2012 , vol. 14, # 23 p. 6000 - 6003

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被引用次数: 51

摘要

... 80 °C. After 24 h, the mixture was cooled to room temperature by water bath and neutralized by 6.2 g NaOH in ... neither olefin exchange nor deuterium incorporation into the allyl fragment is observed after heating 2 with p-allyltoluene in CD3COOD at 80 °C for 15 h (Scheme 1 ...