Nanocrystalline MgO for asymmetric Henry and Michael reactions

BM Choudary, KVS Ranganath, U Pal…

文献索引：Choudary, Boyapati M.; Kantam, Mannepalli L.; Ranganath, Kalluri V. S.; Mahendar, Koosam; Sreedhar, Bojja Journal of the American Chemical Society, 2004 , vol. 126, # 11 p. 3396 - 3397

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被引用次数: 203

摘要

Nanomaterials with their three-dimensional structure and defined size and shape are considered to be suitable candidates for proper alignment with prochiral substrates for unidirectional introduction of reacting species to induce an asymmetric center. We herein report the design and development of a truly recyclable heterogeneous catalyst, nanocrystalline magnesium oxide, for the asymmetric Henry reaction (AH) to afford chiral ...