Evidence against 1, 2-migrations in aryl cations

P Haberfield, C Cardona, M Bell

文献索引：Haberfield, Paul; Cardona, Claudia; Bell, Mark Journal of Organic Chemistry, 1984 , vol. 49, p. 78 - 79

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被引用次数: 2

摘要

The dediazoniation reaction of arenediazonium ions is regarded as the one instance where a phenyl cation is a reaction intermediate.'$ One may reasonably ask whether there exists in the chemistry of the phenylium ion any behavior analogous to the widespread propensity to neighboring group effects among alkyl catior~ s.~,~ Participation by neighboring hydroxyl to form an epoxide is known in aliphatic chemistry both in the case of dediazoniation6 and in ...