The Journal of organic chemistry

Regioselective oxygenations of S-trans dienes, silyl dienol ethers (SDEs), by triphenyl phosphite ozonide (TPPO) and its mechanistic study

A Mori, M Abe, M Nojima

文献索引：Abe, Manabu; Inakazu, Tomoyasu; Munakata, Johichi; Nojima, Masatomo Journal of the American Chemical Society, 1999 , vol. 121, # 28 p. 6556 - 6562

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被引用次数: 8

摘要

The direct oxygenation of s-trans dienes, silyl dienol ethers (SDEs) 2, by triphenyl phosphite ozonide (TPPO) has been examined in detail. The regioselective oxygenation was found to give hydroperoxide 3, alcohol 4, ketone 5, dimer 6, and peroxy phosphate 7 with