Green Chemistry

Reaction network and mechanism of the synthesis of methylenedianiline over dealuminated Y-type zeolites

M Salzinger, JA Lercher

文献索引：Salzinger, Michael; Lercher, Johannes A. Green Chemistry, 2011 , vol. 13, # 1 p. 149 - 155

全文：HTML全文

被引用次数: 11

摘要

The reaction network and mechanism of the synthesis of methylenedianiline (MDA) from the condensation product of aniline and formaldehyde (aminal) on microporous acidic materials has been elucidated. The first step of the reaction, the decomposition of the aminal to N- benzylanilines, is limited by film diffusion, and the second and significantly slower step, the acid catalyzed rearrangement of these intermediates to MDA, is controlled by ...