Journal of medicinal chemistry

The Osmium Tetroxide Catalyzed Hydroxylation of 1, 4-Dimethylenecyclohexanes

JG Murphy

文献索引：Murphy,J.G. Journal of Medicinal Chemistry, 1966 , vol. 9, p. 157 - 159

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被引用次数: 5

摘要

. January 1966 NEW COMPOUNDS 159 alcohol), 10 ml. of t-butyl alcohol, 2.65 ml. of 1- Vh2s04, and 5.30 ml. of 307, H202 cooled in an ice-salt bath, a solution of 1.96 1111. of 2 in 10 nil. of t-butyl alcohol was added (the solution RC-yuired a deep red-brown color). The temperature wa5 nianitained between 0 and-5', arid at the end of 2 hr., 10 ml. of water and 1.74 nil. of 5 NaOH was added to neutralize the solution (phenolphthalein). Sodium ...