Azo anions in synthesis: α-amino carbanion equivalents from t-butyldiphenyl-methylhydrazones

JE Baldwin, RM Adlington, IM Newington

文献索引：Baldwin, Jack E.; Adlington, Robert M.; Newington, Ian M. Journal of the Chemical Society, Chemical Communications, 1986 , # 2 p. 176 - 178

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被引用次数: 9

摘要

α-Amino carbanion equivalents (NH2) and α-hydrazino anion equivalents (NHNH2) are readily accessible from the C-alkylation products of t-butyldiphenylmethylhydrazones; these azoalkanes can be efficiently transformed into amines, hydrazines, and also alkanes under mild reaction conditions.