Olefins and Diolefins from Allylic Chlorides

AL Henne, H Chanan, A Turk

文献索引：Henne; Chanan; Turk Journal of the American Chemical Society, 1941 , vol. 63, p. 3475

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被引用次数: 29

摘要

Irrespective of cis-trans isomkism, which will not be considered here, most allylic chlorides exist in two forms. Crotyl chloride, for instance, is a mixture of a primary chloride, CH3CH= CHCHa-C1, and a secondary chloride, CHz= CHCHClCHa. This permits the synthesis of two olefins by the reaction with a Grignard derivative, three diolefins by condensation on magnesium, or ten diolefins by condensation of two different allylic halides. In practice ...