Wacker??Type Oxidation of Internal Olefins Using a PdCl2/N, N??Dimethylacetamide Catalyst System under Copper??Free Reaction Conditions

T Mitsudome, K Mizumoto, T Mizugaki…

文献索引：Mitsudome, Takato; Mizumoto, Keiichi; Mizugaki, Tomoo; Jitsukawa, Koichiro; Kaneda, Kiyotomi Angewandte Chemie - International Edition, 2010 , vol. 49, # 7 p. 1238 - 1240

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被引用次数: 57

摘要

Carbonyl groups are key moieties for the construction of carbon skeletons and synthetic intermediates.[1] Oxygenation of olefins is one of the most straightforward routes for the synthesis of carbonyl compounds. The industrially important oxidation of ethylene to acetaldehyde, using a catalyst system consisting of palladium with copper, is commonly known as the Wacker oxidation process.[2–5] Since the discovery of this process, this Pd/ ...