Formation of. alpha.,. beta.-unsaturated ketones from the gas-phase pyrolysis of. alpha.-substituted propargyl esters

WS Trahanovsky, SL Emeis

文献索引：Trahanovsky,W.S.; Emeis,S.L. Journal of the American Chemical Society, 1975 , vol. 97, p. 3773 - 3777

被引用次数: 11

摘要

Abstract: Products from the low pressure ( Torr) gas-phase pyrolysis of the following a- substituted propargyl esters were determined: 1-phenylpropargyl hexanoate (1); 1- methylpropargyl benzoate (2); 1, I-dimethylpropargyl benzoate (3); 1, I-dimethylpropargyl hexanoate (4); 1-propylpropargyl benzoate (5); I-isopropylpropargyl benzoate (8); I- ethynylcyclohexyl benzoate (6); I-ethynylcyclopentyl benzoate (7). With the exception of 7, ...

ZnII??and AuI??Catalyzed Regioselective Hydrative Oxidations...

[Jadhav, Appaso Mahadev; Gawade, Sagar Ashok; Vasu, Dhananjayan; Dateer, Ramesh B.; Liu, Rai-Shung Chemistry - A European Journal, 2014 , vol. 20, # 7 p. 1813 - 1817]

Ruthenium??Catalyzed Functionalization of Pyrroles and Indol...

[Thies, Nora; Hrib, Cristian G.; Haak, Edgar Chemistry - A European Journal, 2012 , vol. 18, # 20 p. 6302 - 6308]

Isomerization of Propargylic Alcohols into α, β??Unsaturated...

[Cadierno, Victorio; Garcia-Garrido, Sergio E.; Gimeno, Jose Advanced Synthesis and Catalysis, 2006 , vol. 348, # 1-2 p. 101 - 110]

Additive-assisted Rupe rearrangement of 1-ethynylcyclohexan-...

[Chang, Yong-Juan; Wang, Zhi-Zhong; Luo, Li-Gang; Dai, Li-Yi Chemical Papers, 2012 , vol. 66, # 1 p. 33 - 38]

Experiments with Ethynylcyclohexanol and Related Compounds

[Hurd; Jones Journal of the American Chemical Society, 1934 , vol. 56, p. 1924,1925]