The Journal of Organic Chemistry

Pyrolysis of 1-(trimethylsilyl)-1-alkanols. New carbene precursors of silylcarbene and phenylcarbene

A Sekiguchi, W Ando

文献索引：Sekiguchi, Akira; Ando, Wataru Journal of Organic Chemistry, 1980 , vol. 45, # 26 p. 5286 - 5290

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被引用次数: 8

摘要

Pyrolysis of bis (trimethylsily1) phenylmethanol gave (trimethylsily1) phenylcarbene by the elimination of trimethylsilanol and the products were compared with those of (trimethylsily1) phenyldiazomethane. Alkylsilylcarbenes obtained from the pyrolyses of 1, l-bis (trimethylsily1)-1-alkanols afforded vinyltrimethylsilanes in high yields.(Trimethylsily1) phenylmethanols were found to be excellent precursors of phenylcarbenes and their ...