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Urea??Based Porous Organic Frameworks: Effective Supports for Catalysis in Neat Water

L Li, Z Chen, H Zhong, R Wang

文献索引:Li, Liuyi; Chen, Zhilin; Zhong, Hong; Wang, Ruihu Chemistry - A European Journal, 2014 , vol. 20, # 11 p. 3050 - 3060

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被引用次数: 30

摘要

Abstract Two urea-based porous organic frameworks, UOF-1 and UOF-2, were synthesized through a urea-forming condensation of 1, 3, 5-benzenetriisocyanate with 1, 4- diaminobenzene and benzidine, respectively. UOF-1 and UOF-2 possess good hydrophilic properties and high scavenging ability for palladium. Their palladium polymers, Pd II/UOF-1 and Pd II/UOF-2, exhibit high catalytic activity and selectivity for Suzuki–Miyaura cross- ...