Halogenobis (N, N-dialkyldithiocarbamato) iron (III) complexes as potential catalysts for halogen addition reactions to alkenes

CA Tsipis, GA Katsoulos, FD Vakoulis

文献索引：Tsipis, Constantinos A.; Katsoulos, George A.; Vakoulis, Fotios D. Journal of the Chemical Society, Chemical Communications, 1985 , # 20 p. 1404 - 1405

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摘要

In the course of our investigations on the reactions of the halogenobis(N, N-dialkyldithiocarbamato)iron(rrI) complexes [Fe(S2CNR2)2X] with halogens, X'2, we have demonstrated that binuclear iron( 111) complexes formulated as [Fe(S2CNR2)2X]2( p-Xr2) can be isolated. 1 The formation of these compounds is represented by the general reaction (1), ... 2[Fe(S2CNR2)2X] + X'2 -+ 2[Fe(S2CNR2)2X] Xr2 (1) ... Figure 1. Structural model of the ...