Oxidation of β-dicarbonyl compounds with tert-butyl hydroperoxide in the presence of vanadyl acetylacetonate

LP Stepovik, MV Gulenova, IA Kalacheva…

文献索引：Stepovik; Gulenova; Kalacheva; Potkina, A. Yu. Russian Journal of General Chemistry, 2011 , vol. 81, # 3 p. 550 - 558

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被引用次数: 3

摘要

Abstract Oxidation of β-dicarbonyl compounds with tert-butyl hydroperoxide in the presence of vanadyl acetylacetonate (benzene, 20° C) involves the activated methylene group with intermediate formation of trioxo derivatives and is accompanied by decomposition of carbon skeleton. The oxidation products are carbon dioxide, carboxylic acids, and tert-butyl and peroxy esters derived from the latter.