The Journal of Organic Chemistry

A novel reaction of benzoyl chlorides in dimethyl sulfoxide

S Thea, G Cevasco

文献索引：Thea, Sergio; Cevasco, Giorgio Journal of Organic Chemistry, 1988 , vol. 53, # 17 p. 4121 - 4122

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被引用次数: 10

摘要

low yield obtained (< I%, estimated spectrophotometric-ally at 425 nm), this reaction was not further investigated. Yields of 3a did not vary significantly as a result of ad-dition of triethylamine (TEA)(entry 3) or anhydrous p-toluenesulfonic acid (PTSA)(entry 3). TEA would pro-mote the ionization of the hydroxyl group of 2a; PTSA would inhibit it. Therefore, it is likely that ionization of the hydroxyl group is not important in the process leading to 3a. ...