Electrocarboxylation of chlorinated aromatic compounds

D Golinske, J Voss, G Adiwidjaja

文献索引：Golinske, Dirk; Voss, Juergen; Adiwidjaja, Gunadi Collection of Czechoslovak Chemical Communications, 2000 , vol. 65, # 6 p. 862 - 880

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被引用次数: 18

摘要

Abstract Chorinated benzenes (1, 4), biphenyls (6, 9), dibenzofurans (10, 15, 17, 18), 2- chlorodibenzo [1, 4] dioxine (24) and 1-chloronaphthalene (26) as well as dibenzofuran (12) and naphthalene (27) themselves were transformed into carboxylic acids by galvanostatic electroreduction in the presence of carbon dioxide (" electrocarboxylation"). Dry DMF was used as solvent, zinc or stainless steel as cathode and magnesium as a sacrificial anode ...

~3%

详细

~65%

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~5%

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~8%

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~77%

~1%

~37%

~13%

详细

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