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Chemistry Letters

Phosphine sulfides as an anchor unit for single molecule junctions

…, Y Tsuji, A Staykov, K Yoshizawa, S Yamaguchi

文献索引:Fukazawa, Aiko; Kiguchi, Manabu; Tange, Satoshi; Ichihashi, Yasunori; Zhao, Qiang; Takahashi, Takuya; Konishi, Tatsuya; Murakoshi, Kei; Tsuji, Yuta; Staykov, Aleksandar; Yoshizawa, Kazunari; Yamaguchi, Shigehiro Chemistry Letters, 2011 , vol. 40, # 2 p. 174 - 176

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被引用次数: 19

摘要

Phenylene and biphenyl compounds with dibenzophosphole sulfide (DBPS) as an anchoring group for single molecule junctions were synthesized. The conductance measurements revealed that the phosphine sulfide indeed acts as an anchoring group for Au electrodes. Theoretical calculations including metal electrodes demonstrated that the LUMO level of the DBPS-terminated biphenyl is close to the Au Fermi level, leading to the ...