Transfer of hydrogen from orthoamides. Synthesis, structure, and reactions of hexahydro-6bH-2a, 4a, 6a-triazacyclopenta [cd] pentalene and perhydro-3a, 6a, 9a- …

JM Erhardt, ER Grover, JD Wuest

文献索引：Erhardt,J.M.; Grover,E.R.; Wuest,J.D. Journal of the American Chemical Society, 1980 , vol. 102, p. 6365

被引用次数: 55

摘要

1 complementary information, we have begun to study other simple compounds rivaling 1, 4- dihydropyridines as reducing agents. Orthoamides were attractive candidates since loss of a proton and two electrons can convert them into stable guanidinium ions (eq 1). Unfortunately, however, this reaction does not ordinarily