On the thermal dissociation of organic compounds. XI. The effects of the substituents on the thermal dissociation of urethans in amine solvent

T Mukaiyama, M Iwanami

文献索引：Mukaiyama; Iwanami Journal of the American Chemical Society, 1957 , vol. 79, p. 73,75

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被引用次数: 46

摘要

These are the types that would be expected to promote hydrazinolysis. The contribution of A should be dependent on the acidity of the alcohol, while the effect of B should be related to the basicity of the alcohol. That C does not play a major role is indicated by the fact that both ammonolysis and hydrazinolysis of esters proceed more slowly in the absence of hydroxylated solvents. In benzene ... D could well account for the results. The extent of formation of D would ...