Journal of fluorine chemistry

Reactions of caesium fluoroxysulphate with organic molecules Part 25. Reactions with ethers

S Stavber, I Košir, M Zupan

文献索引：Stavber, Stojan; Kosir, Iztok; Zupan, Marko Journal of Fluorine Chemistry, 1997 , vol. 85, # 2 p. 183 - 186

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摘要

The reactions of caesium fluoroxysulphate in MeCN suspension at room temperature with di- benzyl, di-alkyl or benzyl-alkyl ethers resulted in oxidative cleavage of the ethers forming pairs of corresponding aldehydes and alcohols, which could be further transformed into acid fluorides under the reaction conditions used. Di-benzyl ether was thus transformed to a mixture of benzyl alcohol, benzaldehyde and benzoyl fluoride as the main products and ...