Kinetics of the gas??phase homogeneous unimolecular elimination of selected ethyl esters of 2??oxo??carboxylic acids

A Reyes, RM Domínguez, M Tosta…

文献索引：Journal of Physical Organic Chemistry, , vol. 24, # 1 p. 74 - 82

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被引用次数: 3

摘要

... Journal of Physical Organic Chemistry: Previous article in issue: A ... Table 7. Comparative kinetic and thermodynamic parameters at 400 °C. Substrate, k 1 × 10 4 (s −1 ), E a (kJ mol −1 ), log A (s −1 ), ΔS ≠ (J mol −1 K), ΔH ≠ (kJ mol −1 ), ΔG ≠ (kJ mol −1 ), Ref. a Overall rate. b ...