First evidence for a Curtius-type rearrangement involving a pentacoordinated atom

A Baceiredo, G Bertrand, JP Majoral…

文献索引：Baceiredo,A.; Bertrand,G.; Majoral,J.P. Journal of the American Chemical Society, 1984 , vol. 106, p. 7065

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被引用次数: 10

摘要

Abstract: The photolytic behavior of four X5 phosphorus azides derivatives was investigated to study the scope and limitation of the Curtius rearrangement involving an azide group bonded to a pentacoordinated atom. Three different types of reaction were observed depending on the nature of the phosphorus substituents:(i) expected Curtius-type rearrangements which lead either to an exo-or endocyclic A4 phosphorus nitrogen double ...