The oxygen effect in the reaction of bromine with neopentane, t-butylbenzene and trimethylacetic acid

MS Kharasch, MZ Fineman

文献索引：Kharasch; Fineman Journal of the American Chemical Society, 1941 , vol. 63, p. 2778

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被引用次数: 3

摘要

Rotations. 0.100 g. of acid made up to 25 cc. with ti- butanol at 30" gave CYD -0.54'; after refluxing for thirty- four and one-quarter hours, -0.38"; sixty-two hours, -0.30'; one hundred five hours, -0.225'; one hundred thirty-six hours, -0.13'. The half-life period calculated on the basis of a uni- molecular reversible reaction is around seventy hours. Summary 1. p-Chloro-p- (2-methyl- 1-naphthyl)-acrylic acid and p-chloro-p- (2-methyl- 1-naphthyl)-a- methylacrylic ...