Tetrahedron letters

A mild preparation of α-halo-α, β-enones from cyclic enones

G Righi, P Bovicelli, A Sperandio

文献索引：Righi, Giuliana; Bovicelli, Paolo; Sperandio, Anna Tetrahedron Letters, 1999 , vol. 40, # 32 p. 5889 - 5892

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被引用次数: 22

摘要

A simple one pot procedure for the selective transformation of cyclic enones into α-halo-α, β- enones is reported using dimethyldioxirane and metal halides/Amberlyst 15. The method appears particulary appealing for the preparation of labelled molecules for use with the CMIA techinique.