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Journal of fluorine chemistry

Photochemical bromination of arenes. 2. Fluorobenzene derivatives [1]

R Bolton, ESE Owen

文献索引:Bolton, Roger; Owen, Elaine S. E. Journal of Fluorine Chemistry, 1990 , vol. 46, # 3 p. 393 - 406

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被引用次数: 6

摘要

Abstract Photochemically induced reaction of fluorobenzene and a range of polyfluorobenzenes, both in an excess of the arene and with fluorotrichloromethane as solvent, gave isolable adducts only with fluorobenzene, the isomeric difluorobenzenes, and in very small yield with 1, 3, 5-tri-fluorobenzene. These adducts were identified by combustion analysis, mass spectrometry, and nmr techniques (1 H, 19 C, 19 F). In every ...