Origins of stereoselectivity in radical additions: reactions of alkenes and radicals bearing oxazolidine and thiazolidine amide groups
…, IJ Rosenstein, RA Breyer, JD Bruhnke…
文献索引：Porter, Ned A.; Rosenstein, Ian J.; Breyer, Robert A.; Bruhnke, John D.; Wu, Wen-Xue; McPhail, Andrew T. Journal of the American Chemical Society, 1992 , vol. 114, # 20 p. 7664 - 7676
Abstract: Single-crystal X-ray analysis of four alkenes that undergo stereoselective radical addition reactions are reported. The facial selectivity of radical additions to these alkenes is understood based upon their solid-state conformations. Alkenes which have a conformation placing a group at a position in space sterically protecting one of the faces from addition undergo radical addition with diastereofacial selectivity. The structures of the alkenes are ...
