Journal of the American Chemical Society

Cycloalkylmethyl radicals. 5. 6-to 15-membered rings: ESR studies of ring conformations and stereodynamics

KU Ingold, JC Walton

文献索引：Ingold, K. U.; Walton, J. C. Journal of the American Chemical Society, 1987 , vol. 109, # 23 p. 6937 - 6943

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被引用次数: 15

摘要

Abstract: Cycloalkylmethyl radicals having 7-to 15-membered rings (excluding cyclotetradecylmethyl) have been generated and examined by EPR spectroscopy. All the cycloalkylmethyl radicals from the 9-membered ring upward show two distinguishable conformers, though there may be additional conformers present with cyclodecylmethyl and cyclopentadecylmethyl radicals. All the cycloalkylmethyl radicals from the IO-membered ...