Chemistry Letters

Cobalt carbonyl catalyzed polycarbonylation of polyhalogenated aromatics under photostimulation

T Kashimura, K Kudo, S Mori, N Sugita

文献索引：Kashimura, Tsugunori; Kudo, Kiyoshi; Mori, Sadayuki; Sugita, Nobuyuki Chemistry Letters, 1986 , p. 299 - 302

被引用次数: 23

摘要

Cobalt carbonyl catalyzed polycarbonylation of much less reactive polychlorobenzenes could be easily achieved under photostimulation in aqueous sodium hydroxide. All these reactions could be performed without any organic solvent (in some cases, ethanol was used as a co-solvent) and any phase transfer catalyst.

~31%

~26%

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~22%

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~60%

~14%

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~23%

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~80%

~87%

~84%

~92%

~88%

~57%

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~39%

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~92%

~93%

~96%

~52%

~10%

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~13%

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