Nucleophilic addition to acetylenes in superbasic catalytic systems: XIV. Vinilation of diols in a system CsF-NaOH

LA Oparina, MY Khil'ko, NA Chernyshova…

文献索引：Oparina; Khil'ko; Chernyshova; Shaikhudinova; Parshina; Preiss; Henkelmann; Trofimov Russian Journal of Organic Chemistry, 2005 , vol. 41, # 5 p. 661 - 666

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被引用次数: 2

摘要

Abstract A new catalytic system CsF-NaOH was developed for the synthesis of mono-and divinyl ethers of alkanediols exceeding in efficiency KOH. The nucleophilic addition of diols to acetylene in the presence of this system occurs both at enhance pressure (without solvent, 140–160° C) and atmospheric pressure (in DMSO medium, 100° C) of acetylene. Conditions were established of a selective preparation in a high yield of divinyl ethers ...