Expedient and high-yield synthesis of alkylphos-phonyl bichlorides under mild, neutral conditions: reaction of bis (Trimethylsilyl) alkyl phosphonates with oxalyl …
NN Bhongle, RH Notter, JG Turcotte
文献索引：Bhongle, Nandkumar N.; Notter, Robert H.; Turcotte, Joseph G. Synthetic Communications, 1987 , vol. 17, # 9 p. 1071 - 1076
Nandkumar N. Bhonglea, Robert H. Notterb , and * Joseph G. Turcottea' ... Structurally variant bis(trimethylsily1)alkyl phosphonates were converted in high yields (80-88%, distilled) to the corresponding phosphonyl dichlor- ides upon reaction with (COC1I2/DMF. ... In our on-going investigations of the design ... Although several older methods5-' have been re- ... However, one of the by-products of this reaction is ... We report herein a very efficient ...
