N-arylazoles are important compounds that have extensive applications in biochemical, pharmaceutical, and material fields. [ 1 1. Schlummer , B. ; Scholz , U. Palladium-catalyzed C—N and C—O coupling—A practical guide from an industrial vantage point . Adv. Synth. Catal. 2004 , 346 , 1599 – 1626 . [CrossRef], [Web of Science ®] View all references ] Traditionally, these moieties were prepared by nucleophilic aromatic substitution of ...