Journal of the American Chemical Society

Difluoromalonic Derivatives from Difluoropentane

AL Henne, EG DeWitt

文献索引：Henne; de Witt Journal of the American Chemical Society, 1948 , vol. 70, p. 1549

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被引用次数: 19

摘要

To prepare a fluorinated compound containing an oxygenated function, we have consistently introduced the fluorine atoms in a non-oxygenated compound first, then created the oxygenated function afterwards. In so doing, we have frequently been able to take advantage of the directing power of the fluorinated cluster. The syntheses of CRCO2H, and of HO~ C (CF~). CO2K, are examples of this procedure. lS2