Dalton Transactions

Synthesis of benzoxazolylpyridine nickel complexes and their efficient dimerization of ethylene to α-butene

R Gao, L Xiao, X Hao, WH Sun, F Wang

文献索引：Gao, Rong; Xiao, Liwei; Hao, Xiang; Sun, Wen-Hua; Wang, Fosong Dalton Transactions, 2008 , # 41 p. 5645 - 5651

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被引用次数: 21

摘要

A series of new nickel complexes bearing benzoxazolylpyridines was synthesized and characterized by FT-IR spectroscopic and elemental analysis. The molecular structures of two representative complexes were determined by single-crystal X-ray diffraction. The complex [NiCl2 {2-(2-benzoxazolyl)-6-methylpyridine}](5) is a centrosymmetric dinuclear compound with two penta-coordinated Ni (II) centers, whereas the complex [NiCl2 {2-(5- ...