Tetrahedron

Acylation of α-fluorophosphonoacetate derivatives using magnesium chloride-triethylamine

DY Kim, YM Lee, YJ Choi

文献索引：Kim, Dae Young; Lee, Yong Mi; Choi, Young Jae Tetrahedron, 1999 , vol. 55, # 45 p. 12983 - 12990

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被引用次数: 14

摘要

Acylation of α-fluorophosphonoacetate derivatives in the presence of magnesium chloride- triethylamine has been described. Acylations of triethyl α-fluorophosphonoacetate 1 and diethyl α-fluorophosphonoacetic acid 7 were proceeded under mild conditions to provide α- fluoro-β-keto esters 3 and α-fluoro-β-keto phosphonates 9, respectively, in high yields.